Pearson Edexcel International GCSE in Chemistry · 4CH1

Electronic Configurations and the Periodic Table

Why the table has the shape it has: the group number IS the outer-shell electron count, and everything follows from that.

Topic 1 · Principles of chemistry — one of 18 lessons in this topic, and one of 61 in Chemistry.

What this lesson covers in the specification

Incandio is aligned to this specification. It is not published by, endorsed by or affiliated with Pearson, and it reproduces none of Pearson's wording — the statement numbers are given so you can check every lesson against your own copy.

  • 1.18 — How elements are arranged in the Periodic Table: atomic number, groups and periods
  • 1.19 — Deducing the electronic configurations of the first 20 elements from position
  • 1.20 — Using electrical conductivity and acid–base character of oxides to classify elements as metals or non-metals
  • 1.21 — Identifying an element as a metal or non-metal from its position
  • 1.22 — How the electronic configuration of a main group element relates to its position
  • 1.23 — Why elements in the same group have similar chemical properties
  • 1.24 — Why the noble gases do not readily react

1 · Understand it

No exam language yet. The only question this section answers is: do I actually understand what is happening?

The Periodic Table is not a list. It is a map, and its two directions mean different things. Going ACROSS a period, you add one proton and one electron at a time, filling up the same shell. Going DOWN a group, you start a new shell — so the outer-shell count resets to the same number every time.

Electronic configurations of sodium, magnesium and chlorineNa 2,8,1Mg 2,8,2Cl 2,8,7The outer-shell count IS the group number — that is why a group behaves as one family.
Sodium, magnesium and chlorine. Count the electrons in the outermost shell and you have read the group number straight off.

Filling the shells for the first 20 elements

  1. First shell holds up to 2 electrons.
  2. Second shell holds up to 8.
  3. Third shell holds up to 8 (for the first 20 elements).
  4. Fourth shell then begins — potassium is 2,8,8,1 and calcium is 2,8,8,2.
  5. So sodium (11 electrons) is 2,8,1 — and that final 1 is why sodium is in Group 1.

This is the whole reason a group behaves as a family. Lithium, sodium and potassium all have exactly one outer electron. When they react, they all do the same thing — lose that one electron — so they all form 1+ ions and all react in the same way with water. Fluorine, chlorine and bromine all have seven, all need one more, and all form 1− ions.

Think of it like coins in a pocket

Group 1 elements all carry a single loose coin they are eager to give away. Group 7 elements all have a pocket one coin short of full and are eager to take one. Group 0 elements already have exactly the right change — nothing to gain, nothing to give — which is precisely why they do not react. 'Full outer shell' is not a magic phrase; it means there is no transaction available.

2 · Grade 9 Notes

A different job from the section above. You have already understood it; this is the precise set of things to LEARN — definitions to reproduce word for word, processes in order, equations with units, and the answers that score full marks.

The rules of the table

  • Elements are arranged in order of increasing atomic number
  • A GROUP is a vertical column — the group number equals the number of outer-shell electrons
  • A PERIOD is a horizontal row — the period number equals the number of occupied shells
  • Metals are on the left and in the centre; non-metals are on the upper right

Metal or non-metal — the two tests the specification names

  • Electrical conductivity: metals conduct electricity; non-metals generally do not (graphite is the exception)
  • The oxide: metal oxides are basic (many are alkaline in water); non-metal oxides are acidic

Electronic configurations worth memorising

  • Hydrogen 1 · Helium 2 · Lithium 2,1 · Carbon 2,4 · Nitrogen 2,5 · Oxygen 2,6 · Fluorine 2,7 · Neon 2,8
  • Sodium 2,8,1 · Magnesium 2,8,2 · Aluminium 2,8,3 · Silicon 2,8,4 · Phosphorus 2,8,5 · Sulfur 2,8,6 · Chlorine 2,8,7 · Argon 2,8,8
  • Potassium 2,8,8,1 · Calcium 2,8,8,2

Learn this definition · Why a group reacts alike

Elements in the same group have the same number of electrons in their outer shell, so they react in the same way and form ions with the same charge.

Learn this definition · Why the noble gases are unreactive

Group 0 elements have a full outer shell of electrons, so they have no tendency to lose, gain or share electrons.

Not this: 'Noble gases are unreactive because they are heavy / because they are gases.'

This: It is entirely about the full outer shell. Helium has only two electrons and is one of the lightest elements, yet it is the least reactive of all.

3 · Prove it — the five questions

The five questions climb Grade 6 → Grade 7 → Grade 8 → Grade 9 → Grade 9 challenge, and are marked inside Incandio on your own device, by rule, with an authored diagnosis of the mistake you actually made. The mark schemes stay in the app so that the practice is worth doing; the questions themselves are here.

  1. Grade 6 · State [1 mark] — Write the electronic configuration of a magnesium atom, which has 12 electrons. (Type it like 2,8,1.)
  2. Grade 7 · Explain [3 marks] — Explain why lithium, sodium and potassium all react in a similar way with water.
  3. Grade 8 · Explain [3 marks] — An element conducts electricity and its oxide dissolves in water to give a solution of pH 12. Explain what this tells you about the element.
  4. Grade 9 · Explain [3 marks] — Explain why argon does not form compounds, using its electronic configuration.
  5. 9+ · Predict [4 marks] — Element X is in Period 3 and Group 6. Which set of predictions about X is correct?

The people behind this science

Two ways into the same idea — the one who found the pattern and bet on it, and the one who explained why the pattern is there. Inside Incandio each of them answers knowing exactly which lesson you have just finished.

Dmitri Mendeleev — the one who found the pattern and bet on it

Mendeleev arranged the known elements by their properties, then left empty spaces where he believed undiscovered elements must sit — and predicted their densities and melting points in detail. He was right, and that is why the table is a scientific theory rather than a filing system.

  • “Why did you leave gaps rather than simply listing the elements you knew?”
  • “How could you predict the properties of an element nobody had found?”
  • “What convinced other chemists your arrangement was more than coincidence?”
  • “You ordered by atomic mass; we now use atomic number. Where did that change matter?”
  • “Why do elements in the same column behave so alike?”

Niels Bohr — the one who explained why the pattern is there

Mendeleev found the pattern but could not say why it existed. Bohr's shells supplied the reason: the group number IS the outer-electron count, and the period number IS the number of occupied shells. The table's shape is a picture of how electrons fill up.

  • “Why does the group number tell you the number of outer electrons?”
  • “Why does a new period start when a shell is full?”
  • “Why do the noble gases refuse to react at all?”
  • “How does your model explain why Group 1 metals all behave the same way?”
  • “Why did chemists accept a pattern for decades before anyone could explain it?”

Then defend it

On Incandio a lesson is not finished when the questions come out right. You teach the idea back to Ember, an AI apprentice who asks the awkward question, and then you argue it against Dmitri Mendeleev in a structured debate marked against descriptors you can read before you enter. Learn it, teach it, then defend it — all three happen on this page once the app loads.

Carry on through the course